The “web interface” of the emonTx you refer to is most likely the emonESP configuration page. On each emonBase/emonPi there is one active emonhub.conf and that can be edited via ssh command-line or via the emoncms “emonhub config” page.
The EmonHubTx3eInterfacer (by Owen Duffy not Glyn) will work straight “out of the bag” with a recent emonTx as it reuses the serial output designed for the emonESP. The EmonHubSerialInterfacer is the original basic serial interfacer from which the other serial based interfacers are spawned.
Correct, but even simpler, only the 2 Gnd and Rx lines are needed for basic data reporting via emonhub. To that you can add the 3rd 5v line to power both devices from the one ac/dc 5v adapter (still need the 9v ac/ac for voltage sensing though).
The 4th “tx” and 5th “rst” lines are not essential for normal use. But these will be needed to upload (and configure) other firmwares to the emonTx from the Pi, including simple updates.
Not something you need to think about yet. That was said in response to specific questions about loading FW from the Pi. If you may want to be able to update the emonTx at a later date, fit the wires while you’re there (if you have them) and then you can progress on to that later. I think there is some progress in the works regards updating a serially connected emonTx via the emoncms web pages, so maybe you won’t need to learn any of this and just click a button?
Again, don’t worry too much about any of this right now, in this context “hex” is the pre-compiled firmware file, so called due to it’s .hex extension. One day someone will be asking you where the hell you learnt all this, all it takes is interest and time, the info’s all out there and there are plenty of people happy to talk about it at length. Being aware you do not already know everything and being open to learning is half the battle so you are well on your way 
Thanks Brian, although whether to use that gpio pin for reset is debatable. I deliberately didn’t use the same pin as the RFM2Pi/emonPi’s as I didn’t want accidental over-writing of the FW by the emonPi update routine. As the gpio pin is hardcoded in rpi-avrdude, it may have to be the same pin 7 as Trystan will base the emonTx update on an extension of the current updating process, ie just a different button/option and .hex path/repo.
Actually it could be better the other way round in many instances. Power the Pi with a PSU and the emonTx via the 5v line. The proper Pi PSU’s are far superior to most other PSU of this type including the OEM shop one, plus the Pi has better voltage regulation than the emonTx. This is only a theoretical comparison, I haven’t done side by side tests, but I have always used good Pi PSU’s and powered via the Pi and never had any noise issues or brownouts etc. The Shop PSU powering an emonESP via an emonTx has proven to be somewhat less than perfect for many users and that may not all fall on the fault of the esp. Ether way will work though so the decision can be made on what is to hand to start with, the inter connections are the same regardless.