Hi that’s more or less what I did.
Set all the TRV’s to max then balanced the radiators to get even temps throughout the house.
I had to leave all the TRV’s lower in the bedrooms or everyone sweats to death.
The design temps for those rooms were 18 degrees as per the Octopus radiator schedule so they should be properly sized for that temperature in some of the rooms the kids computers etc provide enough heat and are so well insulated they stay warm. They are only sort of 3x3m’ish.
I did explain to Octopus that the boiler I had installed had weather compensation and had been running for 12 months between 27.5 - 42.4’ish depending on weather and that produced comfortable temps throughout the house.
When they sent me the radiator schedule with a design flow of 50 that did not seem a million miles away from what my boiler was doing I did question the radiator replacements but they insisted they needed to increase the size of six.