Hi Trystan,
Again , to yourself , and all the others , many thanks.
Trying to improve efficiency of my Heat Pump along with the several different oscillation frequencies takes my mind off the seemingly unending struggle to get someone to trust.
The Tank manufacturer has now said that he “does not have the drawings or the test performance for my Heat Pump”.
The Manufacturer now says that they “do not keep the drawings , specifications or test results for old Heat Pumps.”.
My "old Heat Pump was manufactured in 2021.
Whilst it is possible that the original drawings, Specifications and Test results were NOT kept, I feel it is unlikely, and far too convenient for the manufacturer .
The Manufacturer further denies any responsibility for the design , saying that Samsung Designed it , Talk to them. The manufacturer also says that “we recommend 50 litre buffers on all our units, but , talk to Samsung !”.
As we say in Scotland, “it wis’nae me it wis the Big boy doon the road”.
Returning to the specific problems I have with the Heat Pump I have found one of the Oscillations to have a period of 14 minutes. A fourteen minute corresponds to the period of the pump sequence used by field setting 2091, 2092 and 2093 option 4.
I have reset the 2091 and 2093 options to option 3 and reinstated the Volumising tank.
The results , so far are gratifying.

The 2091 option 4 was changed to 2091 option 3 at 1900 along with reinstating the Volumising tank at 1900.
As usual I will wait another day before changing another variable.
The Energy for the same period is

Again , notice the excessive amount of energy used during the oscillations.
The Heat was supplied with TWO Electricity consumption meters, never fitted by my then “installer”.
These meters were amongst the other five major components missing from the original “installation”.
I have used my home made , and, so far as I can see accurate Consumption meter using an Arduino attached to a CT transformer.
I will however, have to install a Calibrated consumption meter on BOTH the Outdoor unit and the indoor unit.
ian