To close this, replacing the cable has resolved the charging issues.
I’ve no idea if the problem was due to the exterior sheathing at the plug being short (with consequently no strain relief for the inner cables nor a full seal with the grommet and the subsequent wetness inside the plug) or the weird tiny bite marks on a section of the cable. Possibly a combination of both.
It might be advisable to check your plugs just in case.
To answer my own question regarding the PP wire, it was cut short and hence floating/unconnected at the plug end of the original cable and therefore replacement with a 3.1 cable rather than 3.2 is perfectly fine in a tethered situation.
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