For COP/SCOP calculation, you want to monitor the total heat output of the heat pump, including losses in the buffer. Therefore, the COP will be lower than if you were to monitor the secondary side of the buffer.

The heat meter body will need to be on the primary flow before the diverter valve and the return temperature sensor will need to be after the last tee, see the section where the heat meter should be fitted in a system with a 4-port buffer highlighted on the diagram below:

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