Thanks Robert

I’ve learnt something today. Turns out the wife unplugged the AC voltage reference adaptor, not the 5v power supply.

I shutdown the Pi using the normal procedure, unplugged both power supplies, plugged in the voltage reference transformer first, then the 5v supply and let it boot up.

Problem is now resolved. It had obviously lost the VRMS defence to give an accurate solar reading that was impacting any other input that depended on that feed.