Ah, you will probably need to update the SD card image for Pi3. Easiest way will be to download fresh latest image: emonSD pre built SD card Download & Change Log · openenergymonitor/emonpi Wiki · GitHub

Here are the manual steps to update to Pi3: Raspberry Pi 3 - Blog | OpenEnergyMonitor

You can check the SD card version by looking at at line in /boot

$ ls /boot | grep emonSD

Latest image is 03May16