Ah, you will probably need to update the SD card image for Pi3. Easiest way will be to download fresh latest image: emonSD pre built SD card Download & Change Log · openenergymonitor/emonpi Wiki · GitHub
Here are the manual steps to update to Pi3: Raspberry Pi 3 - Blog | OpenEnergyMonitor
You can check the SD card version by looking at at line in /boot
$ ls /boot | grep emonSD
Latest image is 03May16